期刊
CURRENT ANALYTICAL CHEMISTRY
卷 7, 期 4, 页码 357-364出版社
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/157341111797183128
关键词
IL-USA-DLLME; Phenylurea herbicides; Water samples; HPLC
资金
- 40th Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry
- Natural Science Foundation of Hebei Province [B2011405007]
An ionic-liquid ultrasound-assisted dispersive liquid-liquid microextraction method (IL-USA-DLLME) was introduced to determine four phenylurea herbicides (i.e., isoproturon, monolinuron, linuron, and diuron) in water samples with high performance liquid chromatography (HPLC). The ionic liquid of 1-hexyl-3-methylimidazolium hexafluorophosphate [HMIMPF6] was dispersed into the aqueous sample solution in fine droplets by ultrasound and was used as the extraction solvent; the phenylurea herbicides were concentrated into the ionic liquid phase. The extraction conditions, such as the volume of the extraction solvent, sonication and centrifugation time, ionic strength, and the emulsification-extraction temperature, were optimized. Under the optimized conditions, the linear correlation coefficient ranged from 0.9954 to 0.9969 for concentration levels of 2-100 mu gL(-1). The good recovery (68-100%) of target analytes was obtained from the water samples. The relative standard deviations (RSDs, n=6) ranged from 2.3-9.5%, and the limits of detection (LODs) for the herbicides were between 0.10 mu gL(-1) and 0.24 mu gL(-1). The applicability of the proposed method was evaluated by the extraction and determination of phenylurea herbicides from several natural water samples.
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