期刊
CRYSTENGCOMM
卷 20, 期 41, 页码 6406-6411出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ce01365a
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资金
- NSERC
Group 16 chalcogen atoms may exhibit Lewis acidic sigma-holes which are able to form attractive supramolecular interactions with Lewis bases via chalcogen bonds (ChB). Interest in ChB is increasing rapidly; however, the potential for anion binding has not been fully explored. Herein we report on the application of chemically robust and stable benzylic selenocynates (1 and 2) for halide ion recognition in the solid state and in solution. Single crystal X-ray structural analysis of various cocrystals reveals structurally important Se center dot center dot center dot X- (X = Cl, Br, I) chalcogen bonds. Changes in the C-13 and Se-77 chemical shifts via NMR spectroscopy show how halide ion recognition influences the local electronic environment of the selenium atoms in solution. Deviations of the interaction from the extension of the C-Se covalent bond are quantified and assessed with the aid of computational chemistry.
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