期刊
CRYSTENGCOMM
卷 16, 期 29, 页码 6530-6533出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ce01031k
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资金
- Science and Industry Endowment Fund (SIEF)
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
- International Synchrotron Access Program (ISAP)
- Australian Government
The water-stable zirconium-tricarboxylate series of frameworks, [Zr6O4(OH)(4)(X)(6)(btc)(2)]center dot nH(2)O, where X = formate (F), acetate (A), or propionate (P), exhibit tunable porosity by virtue of systematic modulation of the chain length of the monocarboxylate ligand X. This modification not only impacts the pore size of the framework, but provides an important avenue for the construction of mixed-linker MOFs.
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