期刊
CRYSTENGCOMM
卷 16, 期 20, 页码 4084-4087出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ce42607f
关键词
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资金
- NSFC [11104107, 91227202]
- National Basic Research Program of China [2011CB808200]
- National Fund for Fostering Talents of basic Science [J1103202]
- CIW
- CDAC
- UNLV
- LLNL
- DOE-NNSA
- DOE-BES
- NSF
- DOE-BES [DE-AC0206CH11357]
Based on the 4,4 '- bipyridine organic linker, metal-organic frameworks of Co-2(4,4 '-bpy)(3)(NO3)(4)center dot xH(2)O (CB-MOF) have been prepared. The pressure-dependent structure evolution of CB-MOF has been investigated up to 11 GPa. An isostructural phase transition was observed at about 6 GPa followed by negative compressibility along the b axis.
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