期刊
CRYSTENGCOMM
卷 16, 期 29, 页码 6547-6551出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ce00369a
关键词
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资金
- International Cooperation of the Ministry of Science and Technology of China [2011DFA50530]
- National Nature Science Foundation of China [21104052, 21374072, 21374068]
- Qing Lan Project
- program of Innovative Research Team of Soochow University
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
A novel azobenzene (Azo) monomer was synthesized and employed to produce Azo-containing covalent organic frameworks (Azo-COF) through the borate ester formation reaction. The trans-to-cis photoisomerization of Azo units in Azo-COF occurred under irradiation with 365 nm UV light. The photoisomerization of Azo units could decrease the crystallinity of Azo-COF but could not change the pore size of Azo-COF.
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