4.7 Article

Targeted synthesis of a mesoporous triptycene-derived covalent organic framework

期刊

CRYSTENGCOMM
卷 15, 期 8, 页码 1524-1527

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ce26487k

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  1. U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering [DE-SC0002576]
  2. Higher Education Commission, Islamabad, Pakistan
  3. Ministry of National Education of Turkey

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The synthesis and characterization of a highly porous triptycene-derived covalent organic framework (TDCOF-5) and its performance in small gas storage are reported. TDCOF-5 crystallizes into a 2D mesoporous network that contains accessible boron sites, exhibits high surface area (SA(Lang) = 3832 m(2) g(-1)), and high gas uptake under low pressure settings.

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