期刊
CRYSTENGCOMM
卷 15, 期 8, 页码 1528-1531出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ce27017c
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资金
- Office of Basic Energy Sciences, Division of Materials Sciences and Engineering [KC020105-FWP12152]
- U. S. Department of Energy [DE-AC05-76RL01830]
Three novel crystalline forms of cucurbit[6]uril (CB[6], 1) have been identified by fine control of the mixing process of a hydrochloride solution of CB[6] with ethanol. The form that exists in nanoplate particles shows permanent porosity upon desolvation and the highest CO2 uptake (15 wt%) at 298 K and 1 bar among any known solid-state forms of CB[6].
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