期刊
CRYSTENGCOMM
卷 15, 期 35, 页码 6892-6895出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ce40706c
关键词
-
资金
- NSF [CHE-1110967]
- Robert A. Welch Foundation [AH-0033]
A new phthalocyanine and porphyrin based hybrid covalent organic framework, CoPc-PorDBA COF, has been synthesized and its gas storage properties have been measured. The CoPc-PorDBA COF crystallizes into 2D sheets with an eclipsed AA stacking motif, and it showed high surface area (S-BET = 1315 m(2) g(-1)), and can store up to 0.8 wt% of H-2 at 77 K and 1 bar and 0.6 wt% of CH4 at 298 K and 1 bar.
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