4.7 Article

New 3D metal phosphonates with bright tunable luminescence for the reversible sensing of nitrobenzene

期刊

CRYSTENGCOMM
卷 14, 期 18, 页码 5761-5764

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ce25608h

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  1. State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences (CAS)
  2. National Science Foundation of China [21173220, 21073192]

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Two isomorphous 3D metal phosphonates, [M-2(H2L)] (M = Zn (1), Co (2); H6L = 1,4-((H2O3PCH2)(HOOCCH2)NCH2)(2) C6H4, are reported; Solid 1 is stable up to 300 degrees C under an air atmosphere, displays bright tunable luminescence and offers reversible sensing of nitrobenzene.

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