期刊
CRYSTENGCOMM
卷 14, 期 11, 页码 3902-3906出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ce25192b
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资金
- Ministerio de Ciencia e Innovacion of Spain [CTQ2011-27929-C02-01]
- ICREA Funding Source: Custom
A thorough statistical analysis of the structures deposited in the Cambridge Structure Database reveals that both the lone-pair-pi and anion-pi interactions occur in a predictive and directional fashion, as evidenced by the careful examination of potential bonding contacts between some common solvent molecules or non-coordinating anions and the electron-rich phenyl or electron-deficient pentafluorophenyl rings. The general directional character of both the lone-pair-pi and anion-pi bonds is clearly observed in the solid state.
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