期刊
CRYSTENGCOMM
卷 14, 期 24, 页码 8352-8356出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ce25133g
关键词
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资金
- National Natural Science Foundation of China [50971079, 51171072]
- National Basic Research Program of China (973) [2012CB932800]
- Program for New Century Excellent Talents in University (MOE)
- Independent Innovation Foundation of Shandong University [2010JQ015]
Nanoporous Cu powders have been fabricated through mechanical alloying and subsequent dealloying. The ligament/channel size of as small as 21.3 +/- 2.7 nm has been obtained by dealloying as-milled Al-Cu powders in a NaOH solution at room temperature, and can be tuned by changing the dealloying temperature. The surface diffusivity of Cu adatoms and mean activation energy have been evaluated based upon surface diffusion controlled coarsening mechanism.
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