期刊
CRYSTENGCOMM
卷 14, 期 14, 页码 4601-4611出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ce25205h
关键词
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资金
- National Natural Science Foundation of Jiangsu Province [BK2010166]
- Industry High Technology Foundation of Jiangsu Province [BE2010144]
- Research Fund for the Doctoral Program of Higher Education, China [20093227110009]
A facile, environmentally friendly synthetic route was developed to prepare nano-Ni core mesoporous-silica shell particles. Ethylenediaminetetraacetic disodium salt (EDTA) was the chelating agent and thus controlled the nucleation rate of the nano-Ni core. In this work, EDTA was used to regulate the reduction rate of nickel acetate. Thereby, by varying the amount of EDTA utilized in reaction medium, the size of nano-Ni can be readily controlled in the range of 40-80 nm. The mesoporous silica shell was fabricated by the Stober method. The nano-Ni core mesoporous-silica shell particles were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). UV spectrophotometry (UV/vis) was used to analyse the growth mechanism of the nano-Ni cores. The as-synthesized nano-Ni core mesoporous silica shell particles were found to show a good catalytic activity towards the reduction of 4-nitrophenol to 4-aminophenol in the presence of an excess amount of NaBH4. The magnetic properties, catalytic mechanism and the possibility of reusability were also investigated.
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