期刊
CRYSTENGCOMM
卷 14, 期 9, 页码 3241-3249出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ce06687d
关键词
-
资金
- National Science Foundation of China [21171148, 91022013, J1103309]
12 new cation-templated complexes, {(BMPB)[AgI3]} (BMPB = 1, 4-bis (methylpyridinium) benzene) (1), {(BPE)(2)[Ag2I6]} (BPE = 1, 2-bis (pyridinium) ethane) (2), {(BPB)[Ag2I4]} (BPB = 1, 4-bis (pyridinium) butane) (3), {(BPH)[Ag2I4]} (BPH = 1, 7-bis (pyridinium) heptane) (4), {(DIBP)[Ag2I4]} (DIBP = 1, 1'-diisopropyl-4, 4'-bipyridinium) (5), {(BPB)[Ag2Br4]} (6), {(BPP)[Ag2Br4]} (=1, 5-bis (pyridinium) pentane) (7), {(DEBP)[Ag2Br4]} (DEBP = 1, 1'-diethyl-4, 4'-bipyridinium) (8), {(BDMLB)[Ag2Br4]} (BDMLB = 1, 4-bis (dimethylimidazolium) butane) (9), {(BPIB center dot Br)[Ag(NCS)(2)]} (BPIB center dot Br = butane phenanthroline bromide) (10), {(DABP)[Ag4I6]} (DABP = 1, 1'-diamyl-4, 4'-bipyridinium) (11), {(BMLB)[Ag2Br2(NCS)(2)]} (BMLB = 1, 4-bis (methylimidazolium) butane) (12), have been synthesized via the self-assembly reaction in solution. Owing to the cooperative template effects from organic cations and halide/thiocyanate anion compounds 1-11 contain a mononuclear anion structure [AgI3](2-) (1), a dimeric anion [Ag2I6](4-) (2), linear chain [Ag2X4](2-) (3-10) and a cubane-like based one-dimensional anionic chain [Ag4I6](2-) (11) that are enclosed into the different cationic channels formed from the pyridinium, phenanthrolinium and imidazolium. While for 12, the compound possesses an infinite 2D supramolecular Epolypseudorotaxane penetrated by geminal dicationic groups.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据