期刊
CRYSTENGCOMM
卷 14, 期 5, 页码 1842-1849出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ce06180e
关键词
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资金
- DFG Center for Functional Nanostructures
- Fulbright Program
Three isostructural two-dimensional coordination polymers of the general formula [Ln(2)(CuL)(3)(H2O)(9)]center dot 5.5H(2)O, where Ln = La (1), Nd (2), and Gd (3), have been synthesized and isolated from aqueous solutions and their single-crystal structures determined by X-ray diffraction. The supramolecular interaction between the non-aromatic metallorings plays an important role in stabilizing the structure of these compounds. The thermal stability, reversible solvent uptake, electronic properties and magnetic studies of these compounds are also reported.
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