期刊
CRYSTENGCOMM
卷 14, 期 10, 页码 3653-3657出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ce06704h
关键词
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资金
- National Basic Research Program of China [2011CB932303, 2011CB933101]
- National Natural Science Foundation of China [51103094, 21073048, 51173031, 91127043]
- Seed Foundation of Tianjin University, Key Laboratory of Optoelectronic Materials Chemistry and Physics, Chinese Academy of Sciences [2008DP173016, 2010KL0010]
- Ministry of Education [20110032120021]
Here we report a novel structure of hierarchical coordination polymers with hyperbranched microspheres. The microspheres were formed by the automatic piling of ultrathin nanoribbons with a thickness of 3.5 +/- 0.1 nm, which resulted from the prior self-assembly of the molecules in a ternary architecture. Briefly, the ultrathin nanoribbons of the lanthanide-EDTA coordination polymers were prepared via an Ostwald ripening process, by a simple hydrothermal treatment in an aqueous mixture of lanthanide cations and EDTA-2Na ligands. To satisfy the requirement of a low surface/interface energy, these ultrathin nanoribbons were then self-assembled into multi-layer nanoribbons, followed by the formation of hyperbranched microspheres. Finally, tricolor (red, green and blue, known as RGB) fluorescent hyperbranched microspheres were also prepared by doping with Eu3+, Tb3+ and Zn2+ as luminescent centers, respectively. Our work shows a simple method to fabricate complex structures of coordination polymers and may inspire further studies on hierarchical architectures of coordination polymers.
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