期刊
CRYSTENGCOMM
卷 14, 期 3, 页码 779-781出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ce06133c
关键词
-
资金
- Iran National Science Foundation
A three-dimensional (3D) porous coordination polymer, [Pb(4-bpdh)(NO3)(H2O)](n) (HMTI-1), has been synthesized under microwave-irradiation (MW) of identical reaction mixtures of Pb(II) salt and 2,5-bis(4-pyridyl)-3,4-diaza-2,4-hexadiene (4-bpdh) at different powers. The microwave synthesis of HMTI-1 has been compared to its conventional synthesis. It has been found that by using MW synthesis HMTI-1 can be obtained in a much shorter synthesis time with improved yield and physical properties. Compound HMTI-1 is stable up to 300 degrees C in the static atmosphere of nitrogen and useful for loading and unloading of guests. In this compound, we successfully loaded the porous crystals and nano-HMTI-1 with I-2 by suspending them in a solution of I-2 in cyclohexane. The delivery of I-2 from HMTI-1 superset of 3I(2) performed in ethanol, a nonaromatic solvent, at room temperature was determined by UV/vis spectroscopy. A comparison of adsorption and desorption rates of iodide between nano and bulk compounds was also conducted.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据