期刊
CRYSTENGCOMM
卷 13, 期 21, 页码 6329-6333出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ce05612c
关键词
-
资金
- FCT, Portugal
- KBN, Poland [N204 280438]
Two new luminescent silver-organic frameworks, [Ag-2(mu(2)-bpca)(mu(3)-PTA) (2)](n)center dot 2nH(2)O (1) and [Ag-4(mu(4)-pma)(mu(2)-PTA)(2)(mu(3)-PTA)(2)]n center dot 8n-H2O (2), have been easily generated from silver(I) oxide, PTA and aromatic carboxylic acids [biphenyl-4,4'-dicarboxylic (H(2)bpca) or pyromellitic (II(4)pma) acid], thus opening up the use of PTA as a versatile N,P-building block in crystal engineering of 3D networks. The topological analysis of 1 reveals a binodal 3,4-connected underlying net with the ins (InS) topology, while 2 represents a tetranodal 3,3,4,4-connected net with a new topology.
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