4.7 Article

Resolution of chiral polyoxoanion[P2Mo18O62](6-) with histidine

期刊

CRYSTENGCOMM
卷 12, 期 7, 页码 2044-2046

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c001160f

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资金

  1. National Natural Science Foundation of China [20701005/20701006]
  2. Postdoctoral station Foundation of Ministry of Education [20060200002]
  3. Testing Foundation of Northeast Normal University (NENU), Science and Technology Creation Foundation of NENU [NENU-STC07009]
  4. Program for Changjiang Scholars and Innovative Research Team in Universities

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The classical Dawson-type racemic polyoxoanions [P2Mo18O62](6-) have been separated in aqueous solution with L,D-histidine, respectively. Two enantiomerically pure compounds: H-3(L-HC6H9N3O2)(3)[P2Mo18O62]center dot 20H(2)O (1a), H-3(D-HC6H9N3O2)(3)[P2Mo18O62]center dot 20H(2)O (1b), have been synthesized.

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