期刊
CRYSTENGCOMM
卷 12, 期 10, 页码 3057-3064出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c004478d
关键词
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资金
- NIOK
- HRSMC
- PTN
- Spanish Ministerio de Ciencia [18-08-463B-750]
- Office of Science, Office of Basic Energy Sciences, of the US Department of Energy [DE-AC02-05CH11231]
- European Union
- CNRS
- University Bordeaux 1
- Conseil Regional d'Aquitaine
Two new 1,3,5-triazine-based ligands, namely 2-chloro-4,6-bis-N-[2-methylsulfanyl-N-(pyridin-2-ylmethyl)aniline]-1,3,5-triazine (cspat) and 2,4,6-tris-N-[N-2-(methylsulfanyl)-N-(pyridin-2-ylmethyl)ethanamine]-1,3,5-triazine (spet), have been purposely designed to favour anion-pi and/or lone pair-pi interactions in their coordination compounds. Three copper coordination compounds from these ligands, i.e. [Cu(cspat)Br-2] (1), [Cu(cspat)(NO3)(2)] (2) and [Cu(Hspet)(NO3)(2)](NO3)center dot 0.5H(2)O (3), have been obtained and their single-crystal X-ray structures have been determined. As expected, the solid-state structures of the three Cu-II compounds are composed of supramolecular networks of anion-pi and/or lone pair-pi non-covalent bonds.
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