期刊
CRYSTENGCOMM
卷 11, 期 10, 页码 2160-2168出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b906620a
关键词
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资金
- Fundacao para a Ciencia e Tecnologia ( Portugal) [PDCT/QUI/64967/2006, PTDC/QUI/65379/2006]
A new compound, [Fe(5-Cl-qsal)(2)][Ni(alpha-tpdt)(2)].CH3CN, where alpha-tpdt = 2,3-thiophenedithiolate and H5-Cl-qsal N-(8-quinolyl)-5-chlorosalicylaldimine, was prepared and structurally and magnetically characterized. The crystal structure is based on an arrangement of alternate layers of [Fe(5-Cl-qsal)(2)](+) cations and [Ni(alpha-tpdt)(2)](-) anions. The magnetic measurements and Mossbauer spectroscopy revealed hybrid behavior in this compound, where a ferromagnetic cluster-glass behavior, ascribed to the anions network, and a spin crossover (SCO) of the [Fe(5-Cl-qsal)(2)](+) cations were observed. The glassy behavior, with a blocking temperature of ca. 7.5 K, results from the disorder in the anionic layer and the competition between ferro- and antiferromagnetic interactions in the anionic layers. The SCO process with T-1/2 = 298 K (high spin fraction = gamma(HS) = 0.5) is rather sluggish in the limits of the conversion (gamma(HS) similar to 0 and gamma(HS) similar to 1), which is attributed to the effect of the anions that seem to restrict somehow the structural distortions of the cations associated with the SCO process.
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