期刊
CRYSTAL RESEARCH AND TECHNOLOGY
卷 47, 期 5, 页码 553-560出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/crat.201100537
关键词
nanopetals; nanoworms; nanoflowers; nanorods; nanoplates; microwave irradiation
资金
- CSIR (South Africa)
ZnO with a flower-like morphology was synthesized using a simple microwave assisted hydrothermal method and used as an acceptor material in hybrid solar cells. X-Ray diffraction and Raman Spectroscopy confirmed the formation of a highly crystalline wurtzite ZnO structure. A highly crystalline and conductive polyaniline with worm-like morphology was synthesized by chemical polymerization of aniline using KH(IO3)2 as an oxidant and was used as a donor material for solar cells. The morphology was probed by using scanning and transmission electron microscopy. Polyaniline with worm-like morphology had a diameter of 160 nm and about 2 mu m long. Solar cell device fabricated from PANI/ZnO active bilayer demonstrated a fill factor of about 22.8%. Upon blending PANI with ZnO the fill factor was improved to 25.6% and efficiency by almost 100 fold when PANI:ZnO 1:1 composite was used as an bulk heterogeneous active layer. The fill factor was further improved to 26.4% when device architecture was changed to diffused bilayer. (C) 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)
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