期刊
CRYSTAL GROWTH & DESIGN
卷 18, 期 10, 页码 5738-5744出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.cgd.8b00895
关键词
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资金
- National Natural Science Foundation of China [21471086]
- K.C. Wong Magna Fund of Ningbo University
A novel anionic Cd(II)-organic framework, {[(CH3)(2)NH2](2)[Cd(H(2)BIPA-TC)(2)]center dot 5(DMF)}(n), has been solvothermally synthesized from a naphthalenediimide-based ligand 5,5'-(1,3,6,8-tetraoxobenzo [Imn] [3,8]phenanthroline-2-7-diyl)bis-1,3-benzenedicarboxylic acid (H(4)BIPA-TC). In the crystal structure, Cd (II) cations link H(2)BIPA-TC2- ligands into a 3-fold interpenetrated 3D network with dia topology. Interestingly, the title compound exhibits a reversible photochromic property and excellent adsorption capacity of Methylene Blue (MB) (149 mg/g) as compared with Rhodamine (RhB), Methyl Orange (MO), and Solvent Yellow 2 (SY2) due to electrostatic interaction in aqueous solution.
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