期刊
CRYSTAL GROWTH & DESIGN
卷 14, 期 3, 页码 1240-1244出版社
AMER CHEMICAL SOC
DOI: 10.1021/cg401760m
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资金
- Department of Science and Technology, New Delhi, India
- Council of Scientific and Industrial Research, New Delhi, India
- Grants-in-Aid for Scientific Research [26600026, 12F02036, 26708007] Funding Source: KAKEN
A novel entangled architecture formed on solvothermal reaction of a imidazolium based bent ligand with Cd(NO3)(2) showing 1D channels decorated with imidazolium groups, is reported. The polymer, {[Cd-2(L)(3)(DMF)(NO3)]-(DMF)(3)(H2O)(8)}(n) (1) (where H2L 1,3-bis(4-carboxyphenyl)imidazolium, DMF = dimethylformamide), shows an interesting 6,3-connected polycatenated structure with channels along the crystallographic b-axis occupied with large number of DMF and water molecules. On removal of these solvent molecules the compound maintains its overall structure. Proton conductivity investigation affords a proton conductivity of 1.3 x 10(-5) Scm(-1) at 25 degrees C and 98% RH when water molecules are introduced into the empty channels.
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