期刊
CRYSTAL GROWTH & DESIGN
卷 14, 期 1, 页码 101-109出版社
AMER CHEMICAL SOC
DOI: 10.1021/cg401208p
关键词
-
资金
- National Nature Science Foundation of China [21101075, 21201081]
- Research Foundation for Excellent Young and Middle-Aged Scientists of Shandong Province [BS2011CL009, BS2012CL008]
- China Postdoctoral Science Foundation [2012M521321]
- Post Doctoral Innovation Project of Shandong Province [201303097]
- High Educational Science & Research Foundation of Shandong Province [J11LB52, J13D58]
- Scientific Research and Technological Development Program of Jining City [20125014]
Two new isostructural quaternary tin(IV) antimony(III) sulfides, [TM(en)(3)][SnSb4S9] [TM = Ni (1), Co (2); en = ethylenediamine], and one mixed-valent thioantimonate (III and V), [Mn(dien)(2)](2)Sb4S9 (3, dien = diethylenetriamine),. have been solvothermally synthesized and structurally characterized. In the structures of 1 and 2, four neighboring SbS3 trigonal pyramids are condensed via corner-sharing to form bow-like Sb4S9 tetramers, which are further interconnected by SnS6 octahedra into the three-dimensional (3D) chiral [SnSb4S9](2-) framework with two types of one-dimensional (ID) chiral channels along the c axis. Compound 3 features a 3D network composed of ID anionic [Sb4S9](4-) chains and [Mn(dien)(2)](2+) complexes interconnected via various hydrogen bonds. The most interesting structural feature of 3 is the presence of two different oxidation states of antimony centers in the ID [Sb4S9](4-) chain with three different types of coordination environments, respectively. The optical absorption spectra indicate that the band gaps of compounds 1, 2, and 3 are 2.07, 2.04, and 2.29 eV, respectively. The thermal stabilities and magnetic properties of the title compounds are also studied.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据