期刊
CRYSTAL GROWTH & DESIGN
卷 12, 期 5, 页码 2162-2165出版社
AMER CHEMICAL SOC
DOI: 10.1021/cg300274n
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资金
- Department of Energy (DOE) [DE-FG02-09ER46650, DE-FG02-08ER46491]
- NSF [CHE-0840483]
- [NSF-DMR-0800415]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0840483] Funding Source: National Science Foundation
- U.S. Department of Energy (DOE) [DE-FG02-08ER46491] Funding Source: U.S. Department of Energy (DOE)
A thermally stable, microporous calcium coordination network shows a reversible 5.75 wt % CO2 uptake at 273 K and 1 atm pressure, with an enthalpy of interaction of similar to 31 kJ/mol and a CO2/N-2 selectivity over 45 under ideal flue gas conditions. The absence of open metal sites in the activated material suggests a different mechanism for selectivity and high interaction energy compared to those for frameworks with open metal sites.
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