期刊
CRYSTAL GROWTH & DESIGN
卷 12, 期 5, 页码 2468-2471出版社
AMER CHEMICAL SOC
DOI: 10.1021/cg3001009
关键词
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资金
- National Basic Research Program of China (973 Programs) [2011CB932504, 2012CB821705]
- NSFC [21073191]
- NSF of Fujian Province [2011J06005]
- CAS [KJCX2-YW-H21]
The assembly of mixing nanosized tris((4-carboxyl)phenylduryl)amine ligand and 4,4'-bipyridine ligand with Zn2+ ion leads to a new microporous framework FIR-2 having pillared-layer structure and unusual (3,4,6)-connected topology, which exhibits large surface area and gas adsorption selectivity for the adsorption of CO2 over N-2 or CH4. The results reveal the potential application of the long tris((4-carboxyl)phenylduryl)amine ligand on the construction of functional microporous metal organic frameworks with interesting structural topologies for gas storage and separation.
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