期刊
CRYSTAL GROWTH & DESIGN
卷 12, 期 11, 页码 5796-5799出版社
AMER CHEMICAL SOC
DOI: 10.1021/cg301343a
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资金
- Netherlands Organization for Scientific Research (Nederlands Organisatie voor Wetenschappelijk Onderzoek (NWO))
Viedma ripening is a process in which a compound that forms a stable racemic conglomerate can be converted to an enantiomerically. pure solid state. Combining this deracemization process with Ostwald's rule of stages, allows Viedma ripening to be extended to a racemic compound for which the conglomerate exists only in a metastable form. This is demonstrated for glutamic acid, a proteinogenic amino acid. Since Ostwald ripening is one of the processes occurring during Viedma ripening, we thus make use of Ostwald twice.
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