期刊
CRYSTAL GROWTH & DESIGN
卷 12, 期 11, 页码 5606-5614出版社
AMER CHEMICAL SOC
DOI: 10.1021/cg3011234
关键词
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资金
- National Natural Science Foundation of China [21075064, 21027013, 21021062, 21275072]
- National Basic Research Program of China [2013CB922102]
Hierarchically micro-/nanostructured coordination polymer [Cu(2,5-PDC)H2O](n) architectures with tunable morphologies have been successfully prepared by rationally adjusting the preparation parameters, such as the reactant concentration, solvent, surfactant, and reaction temperature. Using simple calculations of chosen shaped [Cu(2,5-PDC)H2O](n) architectures, we can obtain several porous copper based inorganic motifs, which show potential applications for the antibacterial field and lithium ion batteries. Therein, CuO-1 can kill the Gram-positive bacteria Bacillus subtilis and Staphylococcus aureus better than other materials. The value for initial discharge capacity of CuO-3 (1160 mAh g(-1)) is higher than the theoretical capacity (674 mAh g(-1)) and most copper oxide materials. Besides, Cu/C composites also show intense application in the antibacterial and Li-ions uptake-release field, which will provide a widely used method to prepare the nanosystem of carbon-coating or carbon-compositing materials by simple calcinations of shaped precursor coordination polymer particles used under the proper temperature.
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