期刊
CRYSTAL GROWTH & DESIGN
卷 12, 期 3, 页码 1091-1094出版社
AMER CHEMICAL SOC
DOI: 10.1021/cg300027h
关键词
-
资金
- National Natural Science Foundation of China [21071127, 20501017, J0830412]
- Program for New Century Excellent Talents in University [NCET-10-0139]
- Natural Science Foundation of Henan Education Department [2009A150028, 2011A150029]
Two new metal organic frameworks, {[Co-3-(mu(3)-DMPhIDC)(2)(H2O)(6)]center dot 2H(2)O}(n) (1) and {[Mn-5(mu(3)-DMPhIDC)(2)-(mu(2)-HDMPhIDC)(2)(Phen)(5)]center dot 2CH(3) OH center dot 3H(2)O}(n) (2) (H3DMPhIDC = 2-(3,4-dimethylphenyl)-1H-imidazole-4,5-dicarboxylic acid, Phen = 1,10-phenanthroline), have been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, elemental analyses, X-ray powder diffraction (XRPD), thermal analyses, and IR spectra. Polymer 1 is an enchanting three-dimensional network containing infinite one-dimensional-hexagonal channels and [Co-2(DMPhIDC)](6) cages, which have two interpenetrating nets topology. Polymer 2 exhibits a two-dimensional framework, which is composed of left- and right-handed helices pillared by Mn2+ linkages. Antiferromagnetic coupling exists between the Co(II) ions or Mn(II) ions in 1 or 2, respectively.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据