期刊
CRYSTAL GROWTH & DESIGN
卷 11, 期 12, 页码 5362-5369出版社
AMER CHEMICAL SOC
DOI: 10.1021/cg2009539
关键词
-
资金
- Department of Science and Technology (DST-FIST), Government of India
In our present study, we attempted to grow the single crystals of (2E)-1-(4-chlorophenyl)-3-[4-(methylsulfanyl)phenyl]prop-2-en-1-one by making use of the slow evaporation solution growth technique at room temperature. But the single crystal X-ray diffraction technique revealed that the grown crystal was a co-crystal with molecular formula C16H13Br0.66Cl0.34OS (4Br4MSP/4Cl4MSP). The presence of functional groups in the molecular structure is confirmed by Fourier transform infrared (FT-IR) spectroscopy. The UV-vis-NIR absorption spectrum shows that this co-crystal has a good transparency window for optical application. Second harmonic generation (SHG) analysis was done to explore nonlinear optical (NLO) characteristics of the material, and the co-crystal was found to have the highest SHG efficiency when compared with all the co-crystals reported in the literature.
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