期刊
CRYSTAL GROWTH & DESIGN
卷 11, 期 3, 页码 820-826出版社
AMER CHEMICAL SOC
DOI: 10.1021/cg101464j
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资金
- EPSRC
- Engineering and Physical Sciences Research Council [EP/E031153/1] Funding Source: researchfish
- EPSRC [EP/E031153/1] Funding Source: UKRI
The remarkable room temperature structure of trimethyltin hydroxide comprises a total of 32 crystallographically independent SnMe3OH units arranged in four independent coordination polymer strands. We suggest that a Z' = 4 value is more appropriate than Z' = 32, reflecting the polymeric structure of the compound. DSC, single crystal and XRPD studies show that on cooling below ca. 160 K the structure undergoes a first order phase change to a symmetric Z' = 1 structure with just one crystallographically unique SnMe3OH unit. The phase change is reversible, and on warming past 176 K the high Z' structure is regenerated, in an endothermic transition. The Z' = 1 and 4 structures are an enantiotropic pair, and trimethyltin hydroxide represents a case where the higher Z' structure is the most stable form at high temperature with the high Z' value possibly arising from a consideration of the dynamics of the crystal as a whole.
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