期刊
CRYSTAL GROWTH & DESIGN
卷 11, 期 11, 页码 4904-4919出版社
AMER CHEMICAL SOC
DOI: 10.1021/cg200751m
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资金
- EPSRC
- EPSRC [EP/E031153/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/E031153/1] Funding Source: researchfish
An enantiotropic pair of polyrnorphs of (H-2-o-PDA(2+))(4)(H5O2+)(SO42)(4)(HSO4-)center dot 2H(2)O (1) interconvert at 140-142 K with a concomitant change in Z'. The details of the structural change are studied by single-crystal X-ray and neutron diffraction which shows that both forms are close packed with the difference resulting from the linearization of hydrogen bonds at low temperature as part of an extensive charge-assisted hydrogen-bonding network. The related (H-2-o-PDA(2+))(2)(SO42-)(2)center dot 3H(2)O (2) has also been characterized by single-crystal neutron diffraction and exhibits a disordered flip-flop water chain and short nonbonded O center dot center dot center dot O contacts enforced by NH3+center dot center dot center dot OSO32- hydrogen-bonded bridges. A total of seven other related salts have been isolated and structurally characterized revealing a surprisingly high incidence of Z' > 1 structures as a result of frustration in the charge-assisted hydrogen-bonded network.
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