期刊
CRYSTAL GROWTH & DESIGN
卷 10, 期 3, 页码 1301-1306出版社
AMER CHEMICAL SOC
DOI: 10.1021/cg901347p
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资金
- LANL [20080780PRD2]
- NSF [0934212]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [934212] Funding Source: National Science Foundation
Solvothermal reactions of Zn(NO3)(2)center dot 6H(2)O and alkali (Na, K) chloride with the trigonal-planar ligand benzene-1,3,5-tribenzoic acid (H3BTB) gave rise to two new crystalline porous metal-organic frameworks (MOFs), [Zn3Na2O(BTB)(2)(DMF)(2)](DMF)(H2O) and [Zn2K3(BTB)(2)(HCOO)(DMF)(3)](DMF)(3)(H2O)(2), respectively. Both phases have Zn3Na2(mu(4)-O) and Zn2K2(HCOO) clusters as molecular building block nodes, and they form similar alkali-bridged 2-fold interpenetrated, (3,6)-connected nets with the mineral rtl-c topology. The alkali-bridged interpenetration reduces the flexibility of their interpenetrated nets, affording permanent porosity and high thermal stability. These two MOFs also exhibit high capacities of hydrogen uptake and strong solid fluorescent emissions.
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