期刊
CRYSTAL GROWTH & DESIGN
卷 9, 期 5, 页码 2363-2376出版社
AMER CHEMICAL SOC
DOI: 10.1021/cg801245g
关键词
-
资金
- DGICYT of Spain [CTQ2008-00841/BQU, CTQ2006-09339/BQU]
- Direccio General de Recerca
- Desenvolupament Tecnologic i Innovacio del Govern Balear
- Conselleria d'Economia
- Hisenda i Innovacio
In this manuscript, we report the synthesis and the solid-state characterization of five new Compounds based on the 2-aminopyrimidine building block. Some of them exhibit interesting anion-pi interactions. In addition, we report a high level ab initio study of anion-pi interactions involving 2-methylaminopyrimidine and its dimer. We demonstrate that these compounds are able to interact favorably with anions. The dimer of 2-methylaminopyrimidine interacts with the anion more strongly than the monomer due to cooperativity effects between the noncovalent hydrogen bonding and anion-pi interactions. This pattern, that is, coexistence of hydrogen bonding and anion-pi bonding, is observed experimentally in the solid state.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据