期刊
CRYSTAL GROWTH & DESIGN
卷 9, 期 3, 页码 1590-1598出版社
AMER CHEMICAL SOC
DOI: 10.1021/cg801256h
关键词
-
资金
- NSF [CHE-0313865]
- NSF-MRI [CHE0320848]
Eight coordination polymers of silver Ag(l) derived from bidentate coordinating heteroscorpionate ligands, (4-carboxyphenyl)bis(3,5-dimethylpyrazolyl)methane (L4c) and (3-carboxyphenyl)bis(3,5-dimethylpyrazolyl)methane (L3c), have been synthesized and characterized by X-ray diffraction, ESI-MS, IR spectroscopy, and elemental analysis. By varying the solvent polarity, the protonation state of the uncoordinated carboxylate groups and hence their solid-state interactions can be controlled. While the silver monomers (tectons) possess chirality due to the asymmetric coordination of the achiral ligands to the silver ion, all of the solid-state materials were isolated as racemic mixtures.
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