期刊
CRYSTAL GROWTH & DESIGN
卷 9, 期 11, 页码 4797-4801出版社
AMER CHEMICAL SOC
DOI: 10.1021/cg9006372
关键词
-
资金
- National Natural Science Foundation of China [50872057]
The paper presents three interesting entanglement systems, including two polyrotaxane-like and one interpene-trating frameworks, namely, [Co(L-1)(bpdc)] (1), [Co(L-2)(bpdc)] (2), and [Co(L-3)1.5(bpdc)(H2O)]center dot(L-3) (3), constructed from biphenyl-4,4'-dicarboxylate and bis(imidazole) ligands (L-1 = 1,6-bis(imidazol-1-yl)-hexane, and rods that are interlaced in a parallel fashion to result in 2D -> 2D polyrotaxane-like motifs (L-2 = 1,4-bis(imidazol-1-ylmethyl)benzene and L-3 = 1,4-bis(1-imidazolyl)-benzene)). Both compounds 1 and 2 contain loops. Compound 3 represents the first example of a triply interpenetrated 5-connected 4(4) 6(6) topology network.
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