A novel coordination polymer as positive electrode material for lithium ion battery

A new coordination polymer based on an aromatic carbonyl ligand is prepared and investigated as a positive active material for lithium ion batteries, namely, [Li-2(C6H2O4)] (1). It is synthesized by the dehydration of [Li-2(C6H2)O-4) center dot 2H(2)O] (2). These compounds are characterized by Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), elemental analysis (EA), single crystal X-ray diffraction methods and powder X-ray diffraction (XRD). As positive material, compound 1 has an initial discharge capacity of 176 mAh center dot g(-1) and a columbic efficiency of 93.18% in the first cycle. It might provide a new method for finding new positive-electrode materials in lithium ion batteries.