期刊
JOURNAL OF NATURAL PRODUCTS
卷 78, 期 2, 页码 286-293出版社
AMER CHEMICAL SOC
DOI: 10.1021/np5009152
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资金
- National Natural Science Foundation of China [41130858, 41322037]
- NSFC-Shandong Joint Fund for Marine Science Research Centers [U1406402]
- Special Financial Fund of Innovative Development of Marine Economic Demonstration Project [GD2012-D01-001]
Twelve new chromone derivatives, corynechromones A-L (1-12), were isolated from the sponge-derived fungus Corynespora cassiicola XS-200900I7. Among them, 1/2, 3/4, 5/6, and 7/8 were pairs of epimers. The planar structures were determined by extensive NMR spectroscopic data. The absolute configurations of 1-10 were assigned by the modified Moshers method and TDDFT ECD calculations together with comparison of their CD spectra. These are the first chromone derivatives reported from the genus Corynespora. A possible rule to determine the absolute configurations at C-2 in chromone derivatives by CD was proposed.
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