期刊
CRITICAL REVIEWS IN ANALYTICAL CHEMISTRY
卷 39, 期 3, 页码 189-203出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/10408340903011838
关键词
Voltammetry; solid amalgam electrode; paste amalgam electrode; reference amalgam electrode; amperometric amalgam detector; potentiometry
The review describes working and reference electrodes based on solid and/or paste amalgams and their application for voltammetric, amperometric, and potentiometric determination of both inorganic and organic analytes. Attention is paid to their preparation, pre-treatment and possible modification, and their application in classical voltammetric arrangements, in flowing systems (HPLC-ED, FIA-ED), and in adsorptive transfer stripping voltammetry. The review confirms that amalgam electrodes can successfully substitute mercury electrodes and, in some special cases, offer possibilities not available to mercury electrodes.
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