期刊
CORROSION SCIENCE
卷 143, 期 -, 页码 329-336出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2018.08.027
关键词
Copper; Corrosion inhibition; Printed electronics; Sol-gel; Benzotriazole
资金
- Israel Ministry of Economy [52694-5]
- National Research Foundation, Prime Minister's Office, Sinagpore, under its Campus of Research Excellence and Technological Enterprise (CREATE) Program
The development of printed electronics has gained much attention as an alternative for conventional metal-based electronics, mainly due to the ability to print electronic circuits on plastics and by much cheaper means as compared with conventional microelectronics. Here we report on a single stage formation of a highly corrosion resistance coating with hydrophobic properties on printed-Cu nanoparticles. Our method is based on the synergistic effect of benzotriazole (BTA) as corrosion inhibitor and trimethylsiloxysilicate (TMS) as hydrophobic component. Printed-Cu coated with such TMS/BTA layer exhibited excellent corrosion resistance in 3.5% NaCl solution, reducing the dissolution of Cu into soluble species by one order of magnitude.
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