期刊
CORROSION SCIENCE
卷 85, 期 -, 页码 445-454出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2014.04.046
关键词
Alloy; Polymer; EIS; Polarization; SEM; Acid inhibition
资金
- National Natural Science Foundation of China
- China National Petroleum Corporation Petrochemical Unite Funded Project [U1262111]
The inhibiting performance of beta-Cyclodetrin-modified acrylamide polymer (poly(AM-co-A-beta-CD-co-NaAA)) on X70 steel in 0.5 M H2SO4 solution has been investigated using potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The polarization curves results reveal that polymer acts as a mixed-type inhibitor. The inhibition efficiency is found to increase by increasing the polymer concentration up to maximum 84.9% for 150 mg L-1 at 303 K. The adsorption is confirmed to obey the Langmuir isotherm. The SEM and EDS results demonstrate that X70 surface is protected by beta-Cyclodextrin-modified acrylamide polymer. (C) 2014 Elsevier Ltd. All rights reserved.
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