期刊
CORROSION SCIENCE
卷 63, 期 -, 页码 316-322出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2012.06.011
关键词
Magnesium; SEM; EPMA; Pitting corrosion
资金
- KIST Project [2E23090, 2E22710, 2E229970]
- Seoul RBD program [SS100008']
We examined the corrosion behavior of Mg in Hanks' solution to determine the potential of a biodegradable pure Mg implant. Abrupt corrosion, initiated by Fe impurity, was observed in the latter stage of experimentation in the form of preferred crystallographic pitting (PCP) propagating along the (0001) basal plane in the grain. Herein, we report the mechanism behind PCP corrosion of Mg and evaluate potential solutions to suppress PCP corrosion. In particular, the addition of Mn inhibits PCP initiation by converting Fe impurities to Fe-Mn compounds, while refining the grain size by extrusion reduces PCP propagation. (C) 2012 Elsevier Ltd. All rights reserved.
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