期刊
CORROSION SCIENCE
卷 53, 期 11, 页码 3688-3696出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2011.07.014
关键词
Steel; EIS; SEM; Acid corrosion
4-(N,N-diethylamino)benzaldehyde thiosemicarbazone (DEABT) was studied for its corrosion inhibition property on the corrosion of aged 18 Ni 250 grade maraging steel in 0.67 M phosphoric acid at 30-50 degrees C by potentiodynamic polarization, EIS and weight loss techniques. Inhibition efficiency of DEABT was found to increase with the increase in DEABT concentration and decrease with the increase in temperature. The activation energy E-a and other thermodynamic parameters (Delta G(ads)(0), Delta H-ads(0), Delta S-ads(0)) have been evaluated and discussed. The adsorption of DEABT on aged maraging steel surface obeys the Langmuir adsorption isotherm model and the inhibitor showed mixed type inhibition behavior. (C) 2011 Elsevier Ltd. All rights reserved.
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