A study on new benzotriazole derivatives as inhibitors on copper corrosion in ground water

The corrosion inhibition properties of newly synthesized 1-(2-pyrrole carbonyl)-benzotriazole (PCBT) and 1-(2-thienyl carbonyl)-benzotriazole (TCBT) in combination with the non-ionic surfactant Triton X-100(TX-100) on metallic copper were studied in ground water environment and the results were compared with benzotriazole (BTA). Various electrochemical studies such as open circuit potential (OCP), potentiodynamic polarization, ac impedance and cyclic voltammetric (CV) were made. Surface analytical techniques like FT-IR and XRD were also performed. The results indicated that PCBT is a better corrosion inhibitor for copper and the formulation consisting of PCBT and TX-100 offered improved inhibition efficiency (IE) in a synergistic manner. (C) 2009 Elsevier Ltd. All rights reserved.