期刊
COORDINATION CHEMISTRY REVIEWS
卷 374, 期 -, 页码 387-415出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2018.07.004
关键词
beta-Diketiminate; Univalent aluminum; Aluminum hydride; Aluminacyclopropene; Reactivity; Pentamethylcyclopentadienyl
资金
- National Nature Science Foundation of China [21671018]
- Deutsche Forschungsgemeinschaft [RO224/68-1]
In the last two decades, tremendous progress has been made towards the development of compounds with s- and p-block elements. S-Diketiminate ligands have been widely used in coordination chemistry due to their versatile tunability in both electronic and steric properties. Aluminum complexes stabilized by beta-diketiminate ligands have been widely explored in stoichiometric studies to activate small molecules. This review article highlights the recent progress of aluminum complexes supported by beta-diketiminate ligands and Cp*(pentamethylcyclopentadienyl) substituents with univalent aluminum as reagents as well as aluminum hydrides in reactions. (C) 2018 Published by Elsevier B.V.
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