期刊
COORDINATION CHEMISTRY REVIEWS
卷 255, 期 5-6, 页码 574-590出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2010.10.040
关键词
N-Heterocyclic carbenes; Sulfur; Transition metal complexes; Catalysis; Ionic liquids
资金
- Natural Science and Engineering Research Council of Canada (NSERC)
- Canada Foundation of Innovation (CFI)
- Nova Scotia Research and Innovation Trust (NSRIT)
- Cape Breton University
Donor group functionalized N-heterocyclic carbenes (NHC) are an important class of ligands used in transition metal complex chemistry. Herein, the growing field of sulfur-functionalized NHC compounds and their respective transition metal complexes are described comprehensively. The sulfur-functionalized NHC compounds are categorized by functional groups such as thiolate, thioether, sulfoxide, thiophene, sulfonate and sulfonamide. Chiral compounds and the hemilabile behaviour of sulfur-functionalized NHC compounds are reported. (C) 2010 Elsevier B.V. All rights reserved.
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