Luminescent gold(I) complexes for chemosensing

With the rich spectroscopic and luminescence properties associated with aurophilic Au ... Au interactions, gold(I) complexes have provided an excellent platform for the design of luminescent chemosensors. This review concentrates on our recent exploration of luminescent gold(I) complexes in host-guest chemistry. Through the judicious design and choice of the functional receptor groups, specific chemosensors for cations and/or anions have been obtained. Utilization of sensing mechanisms based on the on-off switching of Au ... Au interactions and photoinduced electron transfer (PET) has been successfully demonstrated. The two-coordinate nature of gold(I) complexes has also been utilized for the design of ditopic receptors through connecting both cation- and anion-binding sites within a single molecule. (C) 2011 Elsevier B.V. All rights reserved.