期刊
COORDINATION CHEMISTRY REVIEWS
卷 253, 期 9-10, 页码 1476-1494出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2008.10.020
关键词
Diiron complexes; Electron transfer; Protonation; Proton reduction; DFT calculations; Hydrogenase; Bioorganometallic chemistry
资金
- ANR
- CNRS
- Universite de Bretagne Occidentale
This review focuses on electron and proton transfers involving hexacarbonyl and substituted {2Fe2S} complexes inspired from the active site of the [FeFe]-hydrogenases ([FeFe]H(2)ases), and on different mechanisms by which the synthetic models catalyze the reduction of protons. Selected aspects of the mechanisms proposed for the biological process on the basis of DFT calculations are also briefly presented. (C) 2008 Elsevier B.V. All rights reserved.
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