期刊
COORDINATION CHEMISTRY REVIEWS
卷 252, 期 3-4, 页码 444-455出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2007.06.002
关键词
oxomanganese clusters; oxygen evolution; ruthenium; water oxidation
资金
- NIGMS NIH HHS [R01 GM032715, R01 GM032715-21A2, R01 GM032715-22, R01 GM032715-23] Funding Source: Medline
In the last 10 years, a number of advances have been made in the study of the oxygen-evolving complex (OEC) of photosystem II (PSII). Along with this new understanding of the natural system has come rapid advance in chemical models of this system. The advance of PSII model chemistry is seen most strikingly in the area of functional models where the few known systems available when this topic was last reviewed has grown into two families of model systems. In concert with this work, numerous mechanistic proposals for photosynthetic water oxidation have been proposed. Here, we review the recent efforts in functional model chemistry of the oxygen-evolving complex of photosystem II. (c) 2007 Elsevier B.V. All rights reserved.
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