期刊
COORDINATION CHEMISTRY REVIEWS
卷 252, 期 5-7, 页码 492-512出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2007.10.009
关键词
hypervalent silicon center; chiral lewis bases; stereoselective reactions; organic catalysts; silyl reagents
In the last few years the possibility of effectively employing relatively simple organic molecules as enantioselective catalysts able to promote reactions with high levels of chemical efficiency and stereocontrol has been demonstrated. In this context chiral Lewis bases play an important role as promoters of a large variety of stereoselective reactions. In the field of silicon-based chemistry several, new metal-free compounds have recently been developed to efficiently catalyze different reactions where hypervalent silicates are involved as intermediates. The review will present the more recent achievements in silicate-mediated stereoselective reactions catalyzed by chiral Lewis bases. (c) 2007 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据